In Kubernetes, StatefulSets are used to create a set of Pods that receive unique, persistent identities. This allows for the control of the order in which replicas start and stop, making it easier to support certain use cases such as stateful applications with persistent storage or networking requirements. Unlike Deployments, which treat all Pods as identical, StatefulSets make assumptions about how stateful resources are managed and configured, requiring manual configuration of persistent identities for Pods accessing stable storage or network resources. The key characteristic that distinguishes StatefulSets from other workload models is the ability to assign a unique identity to each Pod, making it easier to manage complex stateful applications. When to use StatefulSets includes deploying applications that require access to persistent or stable storage, assigning unique network identifiers, and controlling the order in which replicas start and stop. However, they also have limitations such as requiring manual configuration of persistent identities for accessing stable storage or network resources, making them less flexible than Deployments. To create a StatefulSet, you need to define how to run your Pods and associate them with stateful resources, typically using YAML code and specifying unique labels, resources, and configurations for each Pod.